Conversion of 5-hydroxymethylfurfural to a cyclopentanone derivative by ring rearrangement over supported Au nanoparticles.

نویسندگان

  • Junya Ohyama
  • Ryusuke Kanao
  • Akihiko Esaki
  • Atsushi Satsuma
چکیده

Supported Au nanoparticles showed efficient catalytic performance for the ring rearrangement of 5-hydroxymethylfurfural (HMF) to a cyclopentanone derivative, 3-hydroxymethylcyclopentanone (HCPN), by taking advantage of the selective hydrogenation on Au nanoparticles and the Lewis acid catalysis of metal oxide supports. Among various metal oxide supported Au catalysts, the highest yield of HCPN was obtained by using Au/Nb2O5 (86% yield).

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عنوان ژورنال:
  • Chemical communications

دوره 50 42  شماره 

صفحات  -

تاریخ انتشار 2014